Re: ORGLIST:Palladiummohr

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From: Jacob Zabicky (zabicky$##$bgumail.bgu.ac.il)
Date: Fri Jun 11 2004 - 12:03:25 EDT


Dear Martijn

This might be "palladium black". If my emory does not fail me in one of
the early collective volumes of Organic Synthesis there is a method for
preparing this variety of palladium oxide.

Good luck,

Jacob

On Jun 10, 2004, at 12:20, Martijn Slagt wrote:

> Hello,
>
> In an old publication from Chemische Berichte (Chem Ber. 1956, 2025)
> the authors use "palladiummohr" (German) in a simultaneous reduction of
> a nitro and acetyl group on an aromatic ring in acetic acid with
> sulfuric acid and H2. I'm not completely sure if palladiummohr stands
> for palladium on charcoal or for palladium black. Does anyone know for
> sure?
>
> Thanks in advance,
> Martijn
>
>
>
>
> Dr. Martijn Q. Slagt
> Research Chemist
> SYNCOM B.V.
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