ORGLIST: Sandmeyer reaction

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From: Paul Harris (paul.harris$##$rmit.edu.au)
Date: Thu Feb 08 2001 - 00:09:05 EST


Hi all
I am currently trying diaztisation (and subsequent reaction with CN) of =
aromatic amines containing very hydrophobic groups (trifluoromethyl etc) =
and have a lot of trouble dissolving them in acid/water. As a result the =
yields of the bnezonitriles are moderate.
Has anyone tried a such reactions in organic solvents? I know it is not =
such a common thing to do.
Thanks

Paul

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